HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethyl phosphite → Diethyl 3-Bromobenzylphosphonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethyl phosphite | HCID 31215 | — |
| Reactant | 1-Bromo-3-(chloromethyl)benzene | HCID 523059 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Diethyl 3-Bromobenzylphosphonate | HCID 10979718 | — |
Reaction Steps
3-bromobenzyl chloride (shown by the formula (vi)) and triethyl phosphite were put in a three-necked flask equipped with a reflux condenser, to which toluene was added and heated with stirring for 8 hours under reflux. The mixture was purified by the common method, to obtain diethyl 3-bromobenzylphosphonate (shown by the formula (vii)).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07201976B2 |
| Source dataset | uspto-grants-2007_04 |
| ORD ID | ord-083365ed216c416d989de739b47ed3da |
| Source note | uspto-grants-2007_04 |