HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1274519Generated: November 4, 2026
Hexafluoropropylene → HCID 131722199, compound
https://huagongshe.com/reaction/1274519
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hexafluoropropylene | HCID 8302 | — |
| Reactant | 3,3,3-Trifluoro-2-(trifluoromethyl)-1-propene | HCID 91450 | — |
| Reactant | HCID 131722200 | HCID 131722200 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | HCID 131722199 | HCID 131722199 | 34% |
Reaction Steps
Hexafluoroisobutene (HFIB) (32 g, 0.2 mol), aluminum chlorofluoride AlClxFy (5 g) and hexafluoropropene (30 g, 0.2 mol) were charged into a 400 mL Hastelloy™ nickel alloy reactor and agitated at 50° C. for 12 hours. The reaction mixture was poured onto ice, the organic (lower) layer was separated, dried over P2O5 and distilled to give 21 g (34% yield) of (CF3)2CFCH2C(CF3)=CF2, b.p. 80.5-81.5 (see Table 1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06156943 |
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| Source dataset | uspto-grants-2000_12 |
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| ORD ID | ord-0fb974b8f8664467be78c13484607481 |
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| Source note | uspto-grants-2000_12 |
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