Water → HCID 15285890, compound

HRID 1275612Notes

Reaction equation

HRID 1275612 reaction equation
[CH3:1][C:2]1([CH3:26])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([S:14][C:15]3[CH:25]=[CH:24][C:18]([C:19]([O:21][CH2:22][CH3:23])=[O:20])=[CH:17][CH:16]=3)[CH:5]=[CH:4][C:3]1=2.ClCCl.ClC1C=CC=C(C(OO)=[O:38])C=1.[OH2:41]>>[CH3:26][C:2]1([CH3:1])[CH2:11][CH2:10][C:9]([CH3:12])([CH3:13])[C:8]2[CH:7]=[C:6]([S:14]([C:15]3[CH:16]=[CH:17][C:18]([C:19]([O:21][CH2:22][CH3:23])=[O:20])=[CH:24][CH:25]=3)(=[O:38])=[O:41])[CH:5]=[CH:4][C:3]1=2

Participants

5

Reactant 4

HCID 962WaterHCID 6344DichloromethaneHCID 70297m-Chloroperbenzoic acidHCID 10761557HCID 10761557, compound

Product 1

HCID 15285890HCID 15285890, compound

Procedure

1.05 g (2.8 mmol) of ethyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylthio)benzoate and 30 ml of dichloromethane were introduced into a round-bottomed flask, and 2.45 g (7.12 mmol) of meta-chloroperbenzoic acid were then added. The entire contents were stirred at room temperature for two hours, the reaction medium poured into water, extracted with dichloromethane, the organic phase decanted off, dried over magnesium sulfate and evaporated.

Workup

  1. customthe reaction
  2. extractionextracted with dichloromethane
  3. customthe organic phase decanted off
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-c490a3aedbb74157916398b4390d7eeb
Source dataset
uspto-grants-2000_12
Patent number
US06162815

Reaction notes

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