HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl disulfide → HCID 18427287, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl disulfide | HCID 8077 | — |
| Reactant | Tert-Butyl nitrite | HCID 10906 | — |
| Reactant | 5-Amino-2,3-dichloropyridine | HCID 14595219 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 18427287 | HCID 18427287 | — |
Reaction Steps
24.45 g (0.15 mol) of 3-amino-5,6-dichloropyridine in 280 ml of methylene chloride were reacted with 36.6 g (0.3 mol) of diethyl disulfide and 23.2 g (0.225 mol) of tert-butyl nitrite in 130 ml of methylene chloride by a method similar to Example 1, Precursor α. After working up and subsequently washing the crude product with ethanol, 13.3 g of product of value were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06448205B1 |
| Source dataset | uspto-grants-2002_09 |
| ORD ID | ord-b877751b751f4ffaaf3d05e654e96f2e |
| Source note | uspto-grants-2002_09 |