Dichlorodimethylsilane → HCID 66589487, compound

HRID 1279902Notes

Reaction equation

HRID 1279902 reaction equation
[CH2:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH2:4][CH2:3][CH2:2]1.[CH2:14]([Li])[CH2:15][CH2:16][CH3:17].Cl[Si:20](Cl)([CH3:22])[CH3:21]>CCCCCC>[CH:10]1([Si:20]([CH:17]2[C:11]3[CH2:12][C:13]4[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=4)[C:6]=3[CH2:14][CH2:15][CH2:16]2)([CH3:22])[CH3:21])[C:11]2[CH2:12][C:13]3[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=3)[C:6]=2[CH2:7][CH2:8][CH2:9]1

Participants

5

Reactant 3

HCID 6398DichlorodimethylsilaneHCID 5884652,3,4,9-Tetrahydro-1H-fluoreneHCID 178418339Butyllithium

Product 1

HCID 66589487HCID 66589487, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Following the procedure described in example 1 [step (c)], tetrahydrofluorene (17.6 mmol), butyllithium (11 ml of a solution 1.6M in hexane, 17.6 mmol) and dichlorodimethylsilane (1.07 ml, 8.81 mmol) gave a yellow oil.

Workup

  1. customgave a yellow oil

Sources & evidence

ORD record
ord-9f0ef7c4a59a4ae1b57f5ef1d6d90708
Source dataset
uspto-grants-2002_09
Patent number
US06448424B1

Reaction notes

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