HCID 18429306, compound → HCID 18429151, compound

HRID 1280168Notes

Reaction equation

HRID 1280168 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH2:13][CH2:14][OH:15])[CH:7]=[C:8]([N+:10]([O-])=O)[CH:9]=1)([O-])=O>CO.[Pd]>[NH2:1][C:4]1[CH:5]=[C:6]([CH2:13][CH2:14][OH:15])[CH:7]=[C:8]([NH2:10])[CH:9]=1

Participants

4

Reactant 1

HCID 18429306HCID 18429306, compound

Product 1

HCID 18429151HCID 18429151, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 23938PalladiumSolvent

Procedure

3,5-Dinitro-(2-hydroxyethyl)benzene (0.18 g, 0.85 mmol) was dissolved in methanol (50 ml) and hydrogenated over Pd/C (10%) in a Parr apparatus at 60 psi. After complete hydrogen uptake the catalyst was filtered off and the solvent was evaporated which gave a solid residue of 0.10 g (81%).

Workup

  1. filtrationAfter complete hydrogen uptake the catalyst was filtered off
  2. customthe solvent was evaporated which
  3. customgave a solid residue of 0.10 g (81%)

Sources & evidence

ORD record
ord-da8f3045891b45528f9ef4479f69fe1f
Source dataset
uspto-grants-2002_09
Patent number
US06448442B1

Reaction notes

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