HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroxyamine hydrochloride → Hydrochloric Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroxyamine hydrochloride | HCID 443297 | — |
| Reactant | 3-Methyl-12-phenyl-1-aza-1,5,9-cyclododecatriene | HCID 53733089 | — |
| Solvent | Water | HCID 962 | — |
| Product | Hydrochloric Acid | HCID 313 | — |
| Product | 1-Phenyl-10-methyl-1,11-diaminoundecane | HCID 20405353 | — |
| Product | 2-Methyl-11-phenyl-11-amino-undeca-4,8-dienal oxime | HCID 73665702 | — |
Reaction Steps
Reaction of 3-methyl-12-phenyl-1-aza-1,5,9-cyclododecatriene with hydroxylamine hydrochloride, in the presence of hydrochloric acid and water, to 2-methyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime, and hydrogenation of this to give 1-phenyl-10-methyl-1,11-diaminoundecane; b.p. 138°-140° C./1 Pa; nD20 =1.5095.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04258176 |
| Source dataset | uspto-grants-1981_03 |
| ORD ID | ord-4b2f1a7325454aba977a46d165a5196e |
| Source note | uspto-grants-1981_03 |