Hydroxyamine hydrochloride → Hydrochloric Acid

HRID 128045Notes

Reaction equation

HRID 128045 reaction equation
[CH3:1][CH:2]1[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:4]=[CH:3]1.[ClH:20].[NH2:21][OH:22]>O>[ClH:20].[CH3:1][CH:2]([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[NH2:4])[CH:3]=[N:21][OH:22].[C:14]1([CH:5]([NH2:21])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:2]([CH3:1])[CH2:3][NH2:4])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

6

Reactant 2

HCID 443297Hydroxyamine hydrochlorideHCID 537330893-Methyl-12-phenyl-1-aza-1,5,9-cyclododecatriene

Product 3

HCID 313Hydrochloric AcidHCID 204053531-Phenyl-10-methyl-1,11-diaminoundecaneHCID 736657022-Methyl-11-phenyl-11-amino-undeca-4,8-dienal oxime

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Reaction of 3-methyl-12-phenyl-1-aza-1,5,9-cyclododecatriene with hydroxylamine hydrochloride, in the presence of hydrochloric acid and water, to 2-methyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime, and hydrogenation of this to give 1-phenyl-10-methyl-1,11-diaminoundecane; b.p. 138°-140° C./1 Pa; nD20 =1.5095.

Sources & evidence

ORD record
ord-4b2f1a7325454aba977a46d165a5196e
Source dataset
uspto-grants-1981_03
Patent number
US04258176

Reaction notes

Loading…