Sodium Azide → HCID 91208493, compound

HRID 1280693Notes

Reaction equation

HRID 1280693 reaction equation
[CH2:1]([N:8]([CH3:33])[C:9]1[CH:14]=[CH:13][C:12]([C:15]([CH3:29])([CH2:23]OS(C)(=O)=O)[C:16]([N:18]2[CH2:22][CH2:21][CH2:20][CH2:19]2)=[O:17])=[CH:11][C:10]=1[N+:30]([O-:32])=[O:31])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N-:34]=[N+:35]=[N-:36].[Na+]>CN(C)C=O>[CH2:1]([N:8]([CH3:33])[C:9]1[CH:14]=[CH:13][C:12]([C:15]([CH3:29])([CH2:23][N:34]=[N+:35]=[N-:36])[C:16]([N:18]2[CH2:19][CH2:20][CH2:21][CH2:22]2)=[O:17])=[CH:11][C:10]=1[N+:30]([O-:32])=[O:31])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 21193990HCID 21193990, compound

Product 1

HCID 91208493HCID 91208493, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 6b from 2-[4-(N-benzyl-methylamino)-3-nitro-phenyl]-2-methyl-3-methanesulphonyloxy-1-pyrrolidino-propan-1-one and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-1de68621cc8341978a70eb83e4de5ba9
Source dataset
uspto-grants-2002_09
Patent number
US06451832B2

Reaction notes

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