1-Indanone → HCID 57072976, compound

HRID 1280794Notes

Reaction equation

HRID 1280794 reaction equation
[C:1]1(=O)[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3][CH2:2]1.[C:11]([O:15][C:16]([CH3:19])([CH3:18])[CH3:17])(=[O:14])[NH:12][NH2:13]>CO.C(O)(=O)C>[C:16]([O:15][C:11]([NH:12][N:13]=[C:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3][CH2:2]1)=[O:14])([CH3:19])([CH3:18])[CH3:17]

Participants

5

Reactant 2

HCID 67351-IndanoneHCID 70091tert-Butyl carbazate

Product 1

HCID 57072976HCID 57072976, compound

Reagents, catalysts & solvents 2

HCID 176Acetic AcidCatalystHCID 887MethanolSolvent

Procedure

A solution of indan-1-one (5.0 g) and tert-butyl carbazate (5.0 g) in methanol (20 ml) containing glacial acetic acid (1 drop) was boiled and stirred under reflux for 1.5 hours. The mixture was cooled and evaporated under reduced pressure. The residue was recrystallized from ethanol to give indan-1-one tert-butyloxycarbonyl-hydrazone.

Workup

  1. temperatureunder reflux for 1.5 hours
  2. temperatureThe mixture was cooled
  3. customevaporated under reduced pressure
  4. customThe residue was recrystallized from ethanol

Sources & evidence

ORD record
ord-b4a076868f2841238a0b1733acdd9373
Source dataset
uspto-grants-2002_09
Patent number
US06451834B1

Reaction notes

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