1-Chloro-2,4-Dinitrobenzene → HCID 86755493, compound

HRID 1281054Notes

Reaction equation

HRID 1281054 reaction equation
[OH:1][CH2:2][C:3]([F:47])([F:46])[C:4]([F:45])([F:44])[C:5]([F:43])([F:42])[C:6]([F:41])([F:40])[C:7]([F:39])([F:38])[C:8]([F:37])([F:36])[C:9]([F:35])([F:34])[C:10]([F:33])([F:32])[CH2:11][O:12][C:13]1([F:31])[C:26]([F:27])=[C:25]([F:28])[C:16]([C:17]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=[O:18])=[C:15]([F:29])[CH:14]1[F:30].[N+:48]([C:51]1[CH:56]=[C:55]([N+:57]([O-:59])=[O:58])[CH:54]=[CH:53][C:52]=1Cl)([O-:50])=[O:49]>CN1C(=O)CCC1>[N+:48]([C:51]1[CH:56]=[C:55]([N+:57]([O-:59])=[O:58])[CH:54]=[CH:53][C:52]=1[O:1][CH2:2][C:3]([F:46])([F:47])[C:4]([F:44])([F:45])[C:5]([F:42])([F:43])[C:6]([F:40])([F:41])[C:7]([F:38])([F:39])[C:8]([F:36])([F:37])[C:9]([F:34])([F:35])[C:10]([F:32])([F:33])[CH2:11][O:12][C:13]1([F:31])[C:14]([F:30])=[C:15]([F:29])[C:16]([C:17]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=[O:18])=[C:25]([F:28])[CH:26]1[F:27])([O-:50])=[O:49]

Participants

4

Reactant 2

HCID 61-Chloro-2,4-DinitrobenzeneHCID 86755494HCID 86755494, compound

Product 1

HCID 86755493HCID 86755493, compound

Reagents, catalysts & solvents 1

HCID 13387N-methyl-2-pyrrolidoneSolvent

Procedure

A solution of 4-(10-Hydroxy-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyloxy)-2,3,4,5,6-pentafluorobenzophenone(7.14 g), 2,4-dinitrochlorobenzene (2.42 g) potassium carbonate (2.76 g) and NMP (15 mL) is heated to 75-80° C. for 24 hrs. The solution is further processed as described in example 2 to give 4-[10-(2,4-dinitrophenoxy)-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyloxy]-2,3,4,5,6-pentafluorobenzophenone.

Sources & evidence

ORD record
ord-c110cf9bcf334e97b805dbc84b110b1d
Source dataset
uspto-grants-2002_09
Patent number
US06451960B1

Reaction notes

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