Carbon Tetrachloride → 9-Bromononanoic Acid

HRID 1281215Notes

Reaction equation

HRID 1281215 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11].I([O-])(=O)(=O)=[O:13].[Na+].C(Cl)(Cl)(Cl)Cl.C(#N)C>[Ru](Cl)(Cl)Cl.O>[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([OH:13])=[O:11]

Participants

7

Reactant 4

HCID 5943Carbon TetrachlorideHCID 6342AcetonitrileHCID 1087001-Nonanol, 9-bromo-HCID 23667635Sodium periodate

Product 1

HCID 5482219-Bromononanoic Acid

Reagents, catalysts & solvents 2

HCID 61850Ruthenium trichlorideCatalystHCID 962WaterSolvent

Procedure

9-Bromononyl alcohol (f) (3.347 g) was reacted with sodium metaperiodate and ruthenium chloride in the mixture of carbon tetrachloride, acetonitrile and water to give 9-bromo nonanoic acid (g).

Sources & evidence

ORD record
ord-2cb90864eac643988c5700e799d39d7f
Source dataset
uspto-grants-2002_09
Patent number
US06452039B1

Reaction notes

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