2,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexene → 2,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

HRID 1283346Notes

Reaction equation

HRID 1283346 reaction equation
CC1CCCC(C)(C)C=1C(O)CC=C.[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:23])([CH3:22])[C:17]=1[CH:24]([OH:29])[CH2:25][C:26]([CH3:28])=[CH2:27]>>[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:22])([CH3:23])[C:17]=1[C:24](=[O:29])[CH2:25][C:26]([CH3:28])=[CH2:27]

Participants

3

Reactant 2

HCID 124203212,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexeneHCID 233380582,6,6-Trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene

Product 1

HCID 233380842,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

Procedure

By replacing hereabove 2,6,6-trimethyl-1-[1-hydroxy-3-butenyl]-1-cyclohexene with 2,6,6-trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene (nD20 = 1.4939; d420 = 0.9270), 2,6,6-trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene was obtained; ndD20 = 1.4862; d420 = 0.9307.

Sources & evidence

ORD record
ord-8124431facd84e38bd14608a1d4f2840
Source dataset
uspto-grants-1976_08
Patent number
US03975310

Reaction notes

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