2-Nitrotoluene → HCID 12906240, compound

HRID 1283779Notes

Reaction equation

HRID 1283779 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH3:10])([O-:3])=[O:2].C(O[CH:14](OCC)[N:15]([CH3:17])[CH3:16])C>>[CH3:14][N:15]([CH3:17])/[CH:16]=[CH:10]/[C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 69442-NitrotolueneHCID 70913Dimethylformamide diethylacetal

Product 1

HCID 12906240HCID 12906240, compound

Procedure

A solution of 27.4 g. of o-nitrotoluene and 31.2 g. of 95% N,N-dimethylformamide diethyl acetal was heated under a nitrogen atmosphere in a 165° oil bath for 22 hours with continuous distillation of the ethanol formed in the reaction through a distillation head and descending condenser.

Workup

  1. distillationwith continuous distillation of the ethanol
  2. customformed in the reaction through a distillation head

Sources & evidence

ORD record
ord-e86314bedd22474e870d687754ccbb5c
Source dataset
uspto-grants-1976_08
Patent number
US03976639

Reaction notes

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