Potassium Cyanide → HCID 21516095, compound

HRID 1284297Notes

Reaction equation

HRID 1284297 reaction equation
C([O:4][CH2:5][CH2:6][NH:7][C:8](=[O:25])[N:9]([CH3:24])[CH:10]1[C:23]2[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=2[O:17][C:16]2[C:11]1=[CH:12][CH:13]=[CH:14][CH:15]=2)(=O)C.[C-]#N.[K+]>CO>[OH:4][CH2:5][CH2:6][NH:7][C:8](=[O:25])[N:9]([CH3:24])[CH:10]1[C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=2[O:17][C:18]2[C:23]1=[CH:22][CH:21]=[CH:20][CH:19]=2

Participants

4

Reactant 2

HCID 9032Potassium CyanideHCID 21516080HCID 21516080, compound

Product 1

HCID 21516095HCID 21516095, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

N'-2-Acetoxyethyl-N-methyl-N-9-xanthenylurea (2.1 g.), methanol (20 ml.) and potassium cyanide (50 mg.) were refluxed for 20 minutes and then evaporated to dryness. Recrystallisation of the residue from benzene and then from methylene chloride gave N'-(2-hydroxyethyl)-N-methyl-N-9-xanthenylurea as a hydrate, m.p. 130°-132°C.

Workup

  1. customevaporated to dryness
  2. customRecrystallisation of the residue from benzene

Sources & evidence

ORD record
ord-b87928d203dc4a74ad8ae643d70c5947
Source dataset
uspto-grants-1976_08
Patent number
US03978226

Reaction notes

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