1H-1,2,4-Triazole → HCID 18956510, compound

HRID 128441Notes

Reaction equation

HRID 128441 reaction equation
[NH:1]1[CH:5]=[N:4][CH:3]=[N:2]1.[OH-].[CH2:7]([N+:11]([CH2:20][CH2:21][CH2:22][CH3:23])([CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH2:9][CH3:10]>>[NH:1]1[CH:5]=[N:4][CH:3]=[N:2]1.[CH2:20]([N+:11]([CH2:7][CH2:8][CH2:9][CH3:10])([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:16][CH2:17][CH2:18][CH3:19])[CH2:21][CH2:22][CH3:23]

Participants

3

Reactant 2

HCID 92571H-1,2,4-TriazoleHCID 2723671Tetrabutylammonium Hydroxide

Product 1

HCID 18956510HCID 18956510, compound

Procedure

7 g of 1H-1,2,4-triazole were dissolved in 65 g of a commercial 40% aqueous solution of tetrabutylammonium hydroxide. The mixture was evaporated in vacuo and 50 ml portions of toluene were added several times to remove the water obtained azeotropically. Finally the viscous product was dried in high vacuum until constant in weight. There was obtained 31.5 g of a yellowish, viscous mass.

Workup

  1. customThe mixture was evaporated in vacuo and 50 ml portions of toluene
  2. additionwere added several times
  3. customto remove the water
  4. customobtained azeotropically
  5. customFinally the viscous product was dried in high vacuum until constant in weight
  6. customThere was obtained 31.5 g of a yellowish, viscous mass

Sources & evidence

ORD record
ord-73770e7a7f8244dfb4264e802afe9e3f
Source dataset
uspto-grants-1981_03
Patent number
US04259505

Reaction notes

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