1-Octene → HCID 67245895, compound

HRID 1284865Notes

Reaction equation

HRID 1284865 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=1.[CH2:11]=[CH:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>>[N+:8]([C:5]1[CH:6]=[CH:7][C:2]([CH:11]=[CH:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[CH:3][CH:4]=1)([O-:10])=[O:9]

Participants

3

Reactant 2

HCID 81251-OcteneHCID 114661-Bromo-4-nitrobenzene

Product 1

HCID 67245895HCID 67245895, compoundYield 67%

Procedure

The procedure described in Example 26 is repeated, but using 5.05 g (25 mmols) of 4-bromonitrobenzene and 4.33 ml (27.5 mmols) of 1-octene. After a reaction time of 10 hours at 130° C. and working up as described in Example 1, distillation of the crude product gives 3.90 g (16.7 mmols) of 4-nitrophenyloctene of boiling point 140°-150° C./27 Pa in the form of a yellow liquid; yield 67% of theory (conversion figure 6700; Pd content 0.01 mol %). The product is a mixture of isomers. Analysis for C14H19NO2 (molecular weight 233.21): calculated C 70.08; H 8.21; N 6.01, found C 71.75; H 8.10; N 6.16.

Workup

  1. customAfter a reaction time of 10 hours
  2. customat 130° C.
  3. distillationas described in Example 1, distillation of the crude product

Sources & evidence

ORD record
ord-682193ce51ea42a1af77c06d0c7e689f
Source dataset
uspto-grants-1986_01
Patent number
US04564479

Reaction notes

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