Thionyl Chloride → HCID 53661285, compound

HRID 1285117Notes

Reaction equation

S(Cl)([Cl:3])=O.[C:5]([C:11]1[CH:29]=[CH:28][C:14]([O:15][CH:16]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[C:17](=O)[OH:18])=[C:13]([Cl:30])[CH:12]=1)([CH2:8][CH2:9][CH3:10])([CH3:7])[CH3:6]>C1(C)C=CC=CC=1>[C:5]([C:11]1[CH:29]=[CH:28][C:14]([O:15][CH:16]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[C:17]([Cl:3])=[O:18])=[C:13]([Cl:30])[CH:12]=1)([CH2:8][CH2:9][CH3:10])([CH3:7])[CH3:6]

Participants

Conditions

Temperature: 60 °C

Procedure

9.7 ml of thionyl chloride was added dropwise with stirring to 34.4 g of 2-(4-t-hexyl-2-chlorophenoxy)capric acid dissolved in 34 ml of toluene heated to 60° C. The reaction was carried out at 60° C. for 2 hours. Excess thionyl chloride and toluene were distilled off under reduced pressure. 40.1 g of 2-(4-t-hexyl-2-chlorophenoxy)capric acid chloride was obtained.

Workup

distillationExcess thionyl chloride and toluene were distilled off under reduced pressure

Sources & evidence

ORD record: ord-5003b79af5d1431a8297f2013c08d450
Source dataset: uspto-grants-1986_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04565777

Reaction notes

Loading…