Methanol → HCID 136399287, compound

HRID 1285283Notes

Reaction equation

HRID 1285283 reaction equation
[OH:1][C:2]1[C:10]([C:11]([CH3:14])([CH3:13])[CH3:12])=[CH:9][C:5]([C:6]([SH:8])=[S:7])=[CH:4][C:3]=1[C:15]([CH3:18])([CH3:17])[CH3:16].CO.[Zn:21]>[Pt].CCOCC>[OH:1][C:2]1[C:10]([C:11]([CH3:13])([CH3:12])[CH3:14])=[CH:9][C:5]([C:6]([S-:8])=[S:7])=[CH:4][C:3]=1[C:15]([CH3:18])([CH3:17])[CH3:16].[OH:1][C:2]1[C:10]([C:11]([CH3:13])([CH3:12])[CH3:14])=[CH:9][C:5]([C:6]([S-:8])=[S:7])=[CH:4][C:3]=1[C:15]([CH3:18])([CH3:17])[CH3:16].[Zn+2:21]

Participants

6

Reactant 3

HCID 887Methanol2×HCID 23994Zinc2×HCID 371148452119-95-6

Product 1

HCID 136399287HCID 136399287, compound

Reagents, catalysts & solvents 2

HCID 23939PlatinumCatalystHCID 3283Diethyl EtherSolvent

Procedure

Zinc bis(4-hydroxy-3,5-di-tert.-butyl dithiobenzoate) was prepared as follows. The acid, 4-hydroxy-3,5-di-tert.-butyl dithiobenzoic acid (0.4 g) was dissolved in 15 ml. of methanol. Zinc wire (1.2 cm2) was made the anode and platinum wire (1.4 cm2) was made the cathode. The methanol/acid mixture was placed in a container housing the wire electrodes and 0.1 g of zinc metal was dissolved in 12 hours using 70 ma current and 12 volts. The resulting zinc bis(4-hydroxy-3,5-di-tert.-butyl dithiobenzoate) was isolated from ether solution.

Workup

  1. customZinc bis(4-hydroxy-3,5-di-tert.-butyl dithiobenzoate) was prepared
  2. dissolutionwas dissolved in 12 hours

Sources & evidence

ORD record
ord-6f0c45e1ae144ed9a9efe621ad9f9e4c
Source dataset
uspto-grants-1986_01
Patent number
US04566982

Reaction notes

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