Indene → HCID 22758162, compound

HRID 1287276Notes

Reaction equation

HRID 1287276 reaction equation
CC(C)([O-])C.[K+].[CH2:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[CH:8]1.[C:16]([O:20][CH2:21][CH2:22][CH2:23][CH3:24])(=[O:19])[CH:17]=[CH2:18]>>[CH2:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9]([CH2:18][CH2:17][C:16]([O:20][CH2:21][CH2:22][CH2:23][CH3:24])=[O:19])=[CH:8]1

Participants

4

Reactant 3

HCID 7219IndeneHCID 8846Butyl AcrylateHCID 23665647Potassium tert-butoxide

Product 1

HCID 22758162HCID 22758162, compound

Procedure

To a mixture of 4-5 g. of solid potassium t-butoxide in 464 g. (4.0 mole) of indene heated to 120° is added dropwise over 11/2 hours 256 g. (2.0 mole) of n-butyl acrylate at 100°-120°. After 1 hour longer at 120°-150°, the mixture is cooled, treated with 25 ml. acetic acid and filtered. Distillation affords 256 g. (57%) of product collected at 143°-160° (2 mm. torr.).

Workup

  1. additionTo a mixture of 4-5 g
  2. additionis added dropwise over 11/2 hours 256 g
  3. customat 100°-120°
  4. temperaturethe mixture is cooled
  5. additiontreated with 25 ml
  6. filtrationacetic acid and filtered
  7. distillationDistillation
  8. customaffords 256 g
  9. custom(57%) of product collected at 143°-160° (2 mm. torr.)

Sources & evidence

ORD record
ord-70305c95e3d149bea91b9c576b7e9956
Source dataset
uspto-grants-1976_10
Patent number
US03984407

Reaction notes

Loading…