Styrene → HCID 135840366, compound

HRID 1288595Notes

Reaction equation

HRID 1288595 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8]([SH:10])=[S:9])([CH3:4])([CH3:3])[CH3:2].[CH2:19]=[CH:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>C1(C)C=CC=CC=1>[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8]([S:10][CH:20]([CH3:19])[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)=[S:9])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 7501StyreneHCID 371148452119-95-6

Product 1

HCID 135840366HCID 135840366, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A solution of 14.1 g (0.05 mol) 3,5-di-t-butyl-4-hydroxydithiobenzoic acid and 10.4 g (0.1 mol) styrene in 100 ml toluene was heated at reflux for about 1 hour. The reaction mixture was filtered through silica gel and evaporated under reduced pressure to give the product, m.p. 70°-72° C. Elemental analysis of the product is tabulated in Table I.

Workup

  1. temperatureat reflux for about 1 hour
  2. filtrationThe reaction mixture was filtered through silica gel
  3. customevaporated under reduced pressure
  4. customto give the product, m.p. 70°-72° C

Sources & evidence

ORD record
ord-b30378a618c84c8b8e01297ab386cc63
Source dataset
uspto-grants-1976_10
Patent number
US03988471

Reaction notes

Loading…