Isobutylene → HCID 135840357, compound

HRID 1288596Notes

Reaction equation

HRID 1288596 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8]([SH:10])=[S:9])([CH3:4])([CH3:3])[CH3:2].[CH3:19][C:20](=[CH2:22])[CH3:21]>C1(C)C=CC=CC=1>[C:1]([C:5]1[CH:6]=[C:7]([CH:11]=[C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:13]=1[OH:14])[C:8]([S:10][C:20]([CH3:22])([CH3:21])[CH3:19])=[S:9])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 8255IsobutyleneHCID 371148452119-95-6

Product 1

HCID 135840357HCID 135840357, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
110 °C

Procedure

A solution of 14.1 g (0.05 mol) 3,5-di-t-butyl-4-hydroxydithiobenzoic acid and 5.6 g (0.1 mol) isobutylene in 20 ml toluene was placed in a glass bomb tube. The tube was sealed and heated at 110° C. for 2 hours. The tube was cooled and opened. The contents were removed and evaporated under reduced pressure to give the product as an orange solid, m.p. 128°-130° C. Elemental analysis of the product is tabulated in Table I.

Workup

  1. customThe tube was sealed
  2. temperatureThe tube was cooled
  3. customThe contents were removed
  4. customevaporated under reduced pressure

Sources & evidence

ORD record
ord-a99932681d354114a44c1a7be5cae216
Source dataset
uspto-grants-1976_10
Patent number
US03988471

Reaction notes

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