Methyl iodide → 3-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,6-dimethylpyridinium iodide

HRID 1289749Notes

Reaction equation

HRID 1289749 reaction equation
[CH3:1][I:2].[CH2:3]([S:9][C:10]1[C:14]([C:15]2[CH:16]=[N:17][C:18]([CH3:21])=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)[CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>CC(C)=O>[I-:2].[CH2:3]([S:9][C:10]1[C:14]([C:15]2[CH:16]=[N+:17]([CH3:1])[C:18]([CH3:21])=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)[CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 190753693-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-6-methylpyridine

Product 1

HCID 190753283-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,6-dimethylpyridinium iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Methyl iodide (1 ml, 15 mmol) was added to a solution of 3-(3-hexylthio-1,2,5-thiadiazol-4-yl)-6-methylpyridine (4 mmol) in acetone (5 ml) and the reaction mixture was stirred at room temperature for 20 h. Evaporation of the reaction mixture gave the crude product, which was used without further purification.

Workup

  1. customEvaporation of the reaction mixture

Sources & evidence

ORD record
ord-051fa5fa7abd4d43bcf6e89a5d8b6320
Source dataset
uspto-grants-1998_05
Patent number
US05750541

Reaction notes

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