p-Toluenesulfonic acid → HCID 53909053, compound

HRID 1290450Notes

Reaction equation

HRID 1290450 reaction equation
[O:1]1[C:5]2([CH2:10][CH2:9][S:8][CH:7](O)[CH2:6]2)[O:4][CH2:3][CH2:2]1.[C:12]([OH:15])(=[S:14])[CH3:13].C1(C)C=CC(S(O)(=O)=O)=CC=1>C(Cl)(Cl)(Cl)Cl>[O:1]1[C:5]2([CH2:10][CH2:9][S:8][CH:7]([S:14][C:12](=[O:15])[CH3:13])[CH2:6]2)[O:4][CH2:3][CH2:2]1

Participants

5

Reactant 3

HCID 6101p-Toluenesulfonic acidHCID 18923997HCID 18923997, compoundHCID 178418634HCID 178418634, compound

Product 1

HCID 53909053HCID 53909053, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of 0.545 g of product from Example 394, 0.23 ml of thioacetic acid, 0.16 g of p-toluenesulfonic acid and 8 ml of carbon tetrachloride is stirred at room temperature for 1 hour. After work up concentration in vacuo gives 0.556 g of the desired product.

Workup

  1. concentrationAfter work up concentration in vacuo

Sources & evidence

ORD record
ord-2038fdd74de44d11bfb8125e4acea131
Source dataset
uspto-grants-1998_05
Patent number
US05750735

Reaction notes

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