HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cesium carbonate → 2-Methylthio-4-chloro-5-nitro-6-(3-dimethylaminocarbonylphenoxy)pyrimidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cesium carbonate | HCID 10796 | — |
| Reactant | 3-hydroxy-N,N-dimethylbenzamide | HCID 637524 | — |
| Reactant | 4,6-Dichloro-2-(methylthio)-5-nitropyrimidine | HCID 11345458 | — |
| Product | 2-Methylthio-4-chloro-5-nitro-6-(3-dimethylaminocarbonylphenoxy)pyrimidine | HCID 22102686 | — |
Reaction Steps
In a similar manner, 2-methylthio-5-nitro-4,6-dichloropyrimidine was treated with 3-(dimethylaminocarbonyl)phenol in the presence of cesium carbonate to afford 2-methylthio-5-nitro-4-chloro-6-(3-dimethylaminocarbonylphenoxy)pyrimidine, a compound of formula (M).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05753635 |
| Source dataset | uspto-grants-1998_05 |
| ORD ID | ord-37f73696a95e4b3aae298dd2aa83f2de |
| Source note | uspto-grants-1998_05 |