Methyl iodide → 3-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

HRID 1291473Notes

Reaction equation

HRID 1291473 reaction equation
[CH3:1][I:2].[CH3:3][C:4]([CH3:19])=[CH:5][CH2:6][O:7][C:8]1[C:12]([C:13]2[CH:14]=[N:15][CH:16]=[CH:17][CH:18]=2)=[N:11][S:10][N:9]=1>CC(C)=O>[I-:2].[CH3:3][C:4]([CH3:19])=[CH:5][CH2:6][O:7][C:8]1[C:12]([C:13]2[CH:14]=[N+:15]([CH3:1])[CH:16]=[CH:17][CH:18]=2)=[N:11][S:10][N:9]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 190753253-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)pyridine

Product 1

HCID 190753893-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A mixture of methyl iodide (1 ml, 15 mmol) and 3-(3-(3-methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)pyridine (3 mmol) in acetone (3 ml) was stirred at room temperature for 18 h. The title compound precipita ted from the solution and was collected by filtration to yield 0.92 g (79%).

Sources & evidence

ORD record
ord-68c878d7d18d4afab4c02cb7bb2ffcb0
Source dataset
uspto-grants-1998_05
Patent number
US05753683

Reaction notes

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