HRID1291976

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5360835

Gallium

结构：[Ga].c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID136138306

未命名化合物

结构：O[Ga].c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID178526210

未命名化合物

PRODUCTS

生成物

结构：c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID86280045

29H,31H-Phthalocyanine

C32H18N8

HCID178526210

未命名化合物

PROCEDURE

实验过程

The present invention provides a process for producing hydroxygallium phthalocyanine crystals, which process comprises reacting a gallium compound with an excess of a compound forming a phthalocyanine ring to prepare gallium phthalocyanine, subjecting the resulting gallium. phthalocyanine to acid pasting to obtain a hydroxygallium phthalocyanine crystal having intense diffraction peaks at Bragg angles (2θ±0.2°) of 6.9°, 13.2° to 14.2°, 16.5°, and 26.4° or of 7.0°, 13.4°, 16.6°, 26.0°, and 26.7° in Cukα characteristic X-ray diffractometry, and transforming the resulting crystal by a solvent treatment into hydroxygallium phthalocyanine crystals having intense diffraction peaks at Bragg angles (2θ±0.2°) of 7.5°, 9.9°, 12.5°, 16.3°, 18.6°, 25.1°, and 28.3° in Cukα characteristic X-ray diffractometry.

WORKUP

后处理

customforming a phthalocyanine ring

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1e0339652afd487bbfe2fc7741c11ad8
来源数据集: uspto-grants-1998_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05756247
来源说明: uspto-grants-1998_05

反应 SMILES

[Ga].[Ga].[CH:3]1[CH:4]=[CH:5][C:6]2[C:7](=[C:9]3[N:41]=[C:40]4[N:42]=[C:33]([C:34]5[CH:35]=[CH:36][CH:37]=[CH:38][C:39]=54)[N:32]=[C:30]4[NH:31][C:23]([C:24]5[CH:25]=[CH:26][CH:27]=[CH:28][C:29]=54)=[N:22][C:20]4=[N:21][C:13]([C:14]5[CH:15]=[CH:16][CH:17]=[CH:18][C:19]=54)=[N:12][C:11]=2[NH:10]3)[CH:8]=1.[OH:43][Ga:44].[CH:45]1[CH:46]=[CH:47][C:48]2[C:49](=[C:51]3[N:83]=[C:82]4[N:84]=[C:75]([C:76]5[CH:77]=[CH:78][CH:79]=[CH:80][C:81]=54)[N:74]=[C:72]4[NH:73][C:65]([C:66]5[CH:67]=[CH:68][CH:69]=[CH:70][C:71]=54)=[N:64][C:62]4=[N:63][C:55]([C:56]5[CH:57]=[CH:58][CH:59]=[CH:60][C:61]=54)=[N:54][C:53]=2[NH:52]3)[CH:50]=1>>[CH:4]1[CH:3]=[CH:8][C:7]2[C:6](=[C:11]3[N:12]=[C:13]4[N:21]=[C:20]([C:19]5[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=54)[N:22]=[C:23]4[NH:31][C:30]([C:29]5[CH:28]=[CH:27][CH:26]=[CH:25][C:24]=54)=[N:32][C:33]4=[N:42][C:40]([C:39]5[CH:38]=[CH:37][CH:36]=[CH:35][C:34]=54)=[N:41][C:9]=2[NH:10]3)[CH:5]=1.[OH:43][Ga:44].[CH:46]1[CH:45]=[CH:50][C:49]2[C:48](=[C:53]3[N:54]=[C:55]4[N:63]=[C:62]([C:61]5[CH:60]=[CH:59][CH:58]=[CH:57][C:56]=54)[N:64]=[C:65]4[NH:73][C:72]([C:71]5[CH:70]=[CH:69][CH:68]=[CH:67][C:66]=54)=[N:74][C:75]4=[N:84][C:82]([C:81]5[CH:80]=[CH:79][CH:78]=[CH:77][C:76]=54)=[N:83][C:51]=2[NH:52]3)[CH:47]=1