HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1292414Generated: October 31, 2026
Sodium Azide → 2,3,4-Tri-O-acetyl-beta-D-fucopyranosyl azide
https://huagongshe.com/reaction/1292414
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | beta-D-Glucopyranosyl azide, 2-(acetylamino)-2-deoxy-, 3,4,6-triacetate | HCID 2725015 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2,3,4-Tri-O-acetyl-beta-D-fucopyranosyl azide | HCID 22850575 | — |
Reaction Steps
A solution of diphenyl(2,3,4-tri-O-acetyl-α-D-fucopyranosyl)-phosphate (2.0 g) in anhydrous dimethylformamide (80 mL) containing sodium azide (2.0 g) was heated to 50° C. for 2 h and processed as described in the synthesis of Compound 5, part c (Experiment 4). The product was purified by chromatography on a column of silica gel using ethyl acetate--hexane (3:8) as eluant to obtain the title compound (1.13 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05756712 |
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| Source dataset | uspto-grants-1998_05 |
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| ORD ID | ord-d681730568c44767b172102a4763fcfb |
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| Source note | uspto-grants-1998_05 |
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