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HRID1292414

反应详情

EQUATION

反应方程式

HRID 1292414 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：CC(=O)N[C@@H]1[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O[C@H]1N=[N+]=[N-]
HCID2725015

β-D-Glucopyranosyl azide, 2-(acetylamino)-2-deoxy-, 3,4,6-triacetate

C14H20N4O8

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](N=[N+]=[N-])O[C@H](C)[C@@H]1OC(C)=O
HCID22850575

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
50 °C

PROCEDURE

实验过程

A solution of diphenyl(2,3,4-tri-O-acetyl-α-D-fucopyranosyl)-phosphate (2.0 g) in anhydrous dimethylformamide (80 mL) containing sodium azide (2.0 g) was heated to 50° C. for 2 h and processed as described in the synthesis of Compound 5, part c (Experiment 4). The product was purified by chromatography on a column of silica gel using ethyl acetate--hexane (3:8) as eluant to obtain the title compound (1.13 g).

WORKUP

后处理

  1. customThe product was purified by chromatography on a column of silica gel