Carbon Dioxide → HCID 178527050, compound

HRID 1292576Notes

Reaction equation

HRID 1292576 reaction equation
[C:1]1([P:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:8]2[CH:13]=[CH:12][C:11]([CH2:14][PH:15](=[O:17])[OH:16])=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(=O)([O-])O.[Na+:28].C(=O)=O>>[C:1]1([P:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:8]2[CH:13]=[CH:12][C:11]([CH2:14][PH:15](=[O:16])[O-:17])=[CH:10][CH:9]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1.[Na+:28]

Participants

4

Reactant 3

HCID 280Carbon DioxideHCID 516892Sodium BicarbonateHCID 178527049HCID 178527049, compound

Product 1

HCID 178527050HCID 178527050, compound

Procedure

15.0 g (44.1 mmol) of (4-diphenylphosphinophenyl)methylphosphinic acid were admixed with 100 ml of a 3.7% strength by weight sodium hydrogen carbonate solution (44.1 mmol of NaHCO3) and stirred at room temperature until CO2 evolution had ceased. The aqueous solution was completely evaporated and dried under reduced presure. This gave 15.6 g (97% of theory) of sodium (4-diphenylphosphinophenyl)methyl-phosphinate. Solubility in water: 590 g/l.

Workup

  1. customThe aqueous solution was completely evaporated
  2. customdried

Sources & evidence

ORD record
ord-8f05ea4d18044106b611b3453e9e8ed1
Source dataset
uspto-grants-1998_05
Patent number
US05756804

Reaction notes

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