4,4-Dimethylpentanoic acid → 4-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane

HRID 129282Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 129282
[C:1]([C:5]12[CH2:12][O:11][C:8]([CH2:13][CH2:14][C:15]([CH3:18])([CH3:17])[CH3:16])([O:9][CH2:10]1)[O:7][CH2:6]2)([CH3:4])([CH3:3])[CH3:2].CC(C)(C)CCC12OCC(CCC)(CO1)C(C#N)O2.CC(C)(C)CCC(O)=O>>[C:1]([C:5]12[CH2:6][O:7][C:8]([C:13]#[C:14][C:15]([CH3:18])([CH3:17])[CH3:16])([O:9][CH2:10]1)[O:11][CH2:12]2)([CH3:4])([CH3:3])[CH3:2]

Komponenten

4

Edukt 3

HCID 142374,4-Dimethylpentanoic acidHCID 193732624-t-Butyl-1-(3,3-dimethylbutyl)-2,6,7-trioxabicyclo[2.2.2]octaneHCID 193733511-(3,3-Dimethylbutyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile

Produkt 1

HCID 193732684-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane

Versuchsvorschrift

Using analogous methodology 4-t-butyl-1-(3,3-dimethylbutyl) -2,6,7-trioxabicyclo[2.2.2 ]octane and 1-(3,3 - dimethylbutyl) -4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile were prepared from 4,4-dimethylpentanoic acid (G. M. Whitesides et al J. Amer. Chem. Soc. 1967, 89, 1135).

Quellen und Nachweise

ORD-Eintrag
ord-09e9824d138a4409ac519506cc25751d
Quelldatensatz
uspto-grants-1995_11
Patentnummer
US05466710

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