Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4,4-Dimethylpentanoic acid → 4-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4,4-Dimethylpentanoic acid | HCID 14237 | — |
| 반응물 | 4-t-Butyl-1-(3,3-dimethylbutyl)-2,6,7-trioxabicyclo[2.2.2]octane | HCID 19373262 | — |
| 반응물 | 1-(3,3-Dimethylbutyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile | HCID 19373351 | — |
| 생성물 | 4-t-Butyl-1-(3,3-dimethylbut-1-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane | HCID 19373268 | — |
반응 단계
Using analogous methodology 4-t-butyl-1-(3,3-dimethylbutyl) -2,6,7-trioxabicyclo[2.2.2 ]octane and 1-(3,3 - dimethylbutyl) -4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane-3-carbonitrile were prepared from 4,4-dimethylpentanoic acid (G. M. Whitesides et al J. Amer. Chem. Soc. 1967, 89, 1135).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05466710 |
| 출처 데이터셋 | uspto-grants-1995_11 |
| ORD ID | ord-09e9824d138a4409ac519506cc25751d |
| 출처 메모 | uspto-grants-1995_11 |