Dimethyl Sulfoxide → HCID 86598999, compound

HRID 1292975Notes

Reaction equation

HRID 1292975 reaction equation
[CH:1]1([C:6]([OH:19])([CH2:9][C:10]([CH3:18])([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH3:11])[CH2:7][OH:8])[CH2:5][CH2:4][CH2:3][CH2:2]1.CS(C)=O>C(N(CC)CC)C>[CH:1]1([C:6]([OH:19])([CH2:9][C:10]([CH3:11])([C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH3:18])[CH:7]=[O:8])[CH2:2][CH2:3][CH2:4][CH2:5]1

Participants

4

Reactant 2

HCID 679Dimethyl SulfoxideHCID 694236952-Cyclopentyl-4-methyl-4-phenylpentane-1,2-diol

Product 1

HCID 86598999HCID 86598999, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

185 mg of 2-cyclopentyl-4-methyl-4-phenyl-1,2-pentanediol is converted with 438 mg of pyridine-sulfur trioxide complex, 2.5 ml of DMSO and 0.5 ml of triethylamine into 160 mg of aldehyde.

Sources & evidence

ORD record
ord-3e48b72266ce4a549fba70829307b111
Source dataset
uspto-grants-2007_07
Patent number
US07238707B2

Reaction notes

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