Pyridine → HCID 131719202, compound

HRID 129367Notes

Reaction equation

HRID 129367 reaction equation
[CH3:1][O:2][CH:3]([O:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1)[CH3:4].C(O[CH2:17][CH2:18][CH2:19]C)=C.N1C=CC=CC=1.S(=O)(=O)(O)O>O1CCOCC1>[CH2:1]([O:2][CH:3]([O:5][C:6]1[CH:7]=[CH:8][C:9]([CH:10]=[CH2:11])=[CH:12][CH:13]=1)[CH3:4])[CH2:17][CH2:18][CH3:19].[OH:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1

Participants

6

Reactant 4

HCID 1049PyridineHCID 1118Sulfuric AcidHCID 8108Butyl vinyl etherHCID 22057201HCID 22057201, compound

Product 1

HCID 131719202HCID 131719202, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

To a solution of poly(p-hydroxystyrene) (4.8 g) obtained in the same manner as described in Synthesis Example 3, (2) and n-butyl vinyl ether (3.0 g) in a mixed solvent (50 ml) of pyridine and 1,4-dioxane, a catalytic amount of conc. sulfuric acid was added, then continued to stir at room temperature for 16 hours. The reaction mixture was treated in the same manner as described in Synthesis Example 2, (3) to give 4.2 g of poly[p-(1-n-butoxyethoxy)styrene/p-hydroxystyrene] as a white powder having Mw 10000 (GPC with polystyrene calibration). The composition of the polymer was found to be p-(1-n-butoxyethoxy)styrene unit and p-hydroxystyrene unit in a molar ratio of 4:6 based on 1HNMR.

Workup

  1. additionThe reaction mixture was treated in the same manner

Sources & evidence

ORD record
ord-b44e109ae79646ba84affb907613c7d3
Source dataset
uspto-grants-1995_11
Patent number
US05468589

Reaction notes

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