HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 1-Carboxy-3-nitro-5-adamantanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | 3-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid | HCID 39239 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 1-Carboxy-3-nitro-5-adamantanol | HCID 22463570 | 80% |
Reaction Steps
In an atmosphere of oxygen, the mixture of 10 mmole of 1-carboxy-3-nitroadamantane, 1 mmole of NHPI, 0.05 mmole of V(AA)3 and 25 mL of acetic acid was allowed to react for 4 hours at 85° C. The reaction products were analyzed by gas-mass spectroscopy, and as a result, 1-carboxy-3-nitro-5-adamantanol was formed in a 80% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | USRE039744E1 |
| Source dataset | uspto-grants-2007_07 |
| ORD ID | ord-42946ffe58bc4a75ba85fef515019366 |
| Source note | uspto-grants-2007_07 |