Sulfuric Acid → 4,4-Diphenylbutan-1-ol

HRID 1297021노트

반응식

HRID 1297021 반응식
[C:1]1([C:7]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)(O)[CH2:8][CH2:9][CH2:10][OH:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(=O)(=O)(O)O>CO.[Pd]>[C:13]1([CH:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[CH2:8][CH2:9][CH2:10][OH:11])[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

참가 물질

5

반응물 2

HCID 1118Sulfuric AcidHCID 966791,1-Diphenylbutane-1,4-diol

생성물 1

HCID 925194,4-Diphenylbutan-1-ol

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

11.2 g (46.2 mmol) of 1,1-diphenyl-1,4-butanediol was hydrogenated (45° C., 5 atm) in 100 ml of methanol in the presence of 0.5 ml of concentrated sulfuric acid and 10% palladium/carbon to obtain the title compound.

출처 및 근거

ORD 기록
ord-d373cd1919ee4ec7b8ad42622650291c
출처 데이터셋
uspto-grants-2007_07
특허 번호
US07247645B2

반응 노트

불러오는 중…