Methanol → HCID 15575966, compound

HRID 1297026Notes

Reaction equation

HRID 1297026 reaction equation
CO.[C:3]1([CH:9]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH2:10][CH:11]=[CH:12][CH2:13][OH:14])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>[H][H].[Pd]>[C:15]1([CH:9]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:10][CH2:11][CH2:12][CH2:13][OH:14])[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

Participants

5

Reactant 2

HCID 887MethanolHCID 53725716HCID 53725716, compound

Product 1

HCID 15575966HCID 15575966, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 178418361HCID 178418361, compoundSolvent

Procedure

10 ml of methanol was added to a mixture of 320 mg (1.34 mmol) of 5,5-diphenyl-2-pentene-1-ol and a catalytic amount of 10% palladium/carbon, and they were stirred in hydrogen atmosphere at room temperature under ambient pressure for 12 hours. The catalyst was filtered out and the obtained filtrate was concentrated under reduced pressure to obtain the unpurified title compound.

Workup

  1. filtrationThe catalyst was filtered out
  2. concentrationthe obtained filtrate was concentrated under reduced pressure

Sources & evidence

ORD record
ord-46b8a7bd2e8c482c8bb8ae20720f8a9c
Source dataset
uspto-grants-2007_07
Patent number
US07247645B2

Reaction notes

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