HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1297537Generated: October 30, 2026
Potassium Carbonate → HCID 23077013, compound
https://huagongshe.com/reaction/1297537
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-(4-Ethylbenzyl)phenol | HCID 11658557 | — |
| Reactant | HCID 69425068 | HCID 69425068 | — |
| Catalyst | Benzyltributylammonium chloride | HCID 159952 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 23077013 | HCID 23077013 | — |
Reaction Steps
2,3,4,6-Tetra-O-acetyl-5-thio-β-D-glucopyranosyl bromide (1) (Tetrahedron, vol. 49, p. 8977, 1993), 2-(4-ethylbenzyl)phenol (9), potassium carbonate and benzyl tri-n-butylammonium chloride were mixed in chloroform and heated at 60° C. However, it was completely impossible to obtain a glycosylation product. 2-(4-Ethylbenzyl)phenyl acetate was obtained as a by-product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07250522B2 |
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| Source dataset | uspto-grants-2007_07 |
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| ORD ID | ord-669e082926dc4531afa2c407c67f397e |
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| Source note | uspto-grants-2007_07 |
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