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HRID1297537

反应详情

EQUATION

反应方程式

HRID 1297537 的结构方程式

REACTANTS

反应物

3
结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：CCc1ccc(Cc2ccccc2O)cc1
HCID11658557

2-(4-ethylbenzyl)phenol

C15H16O

结构：CC(=O)OC[C@H]1S[C@@H](Br)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O
HCID69425068

未命名化合物

PRODUCTS

生成物

1
结构：CCc1ccc(Cc2ccccc2OC(C)=O)cc1
HCID23077013

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCCC[N+](CCCC)(CCCC)Cc1ccccc1.[Cl-]
催化剂HCID159952

Benzyl trialkyl ammonium compound C4:C4:C4 (BTAAC C4:C4:C4)

C19H34ClN

结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

CONDITIONS

反应条件

温度
60 °C

PROCEDURE

实验过程

2,3,4,6-Tetra-O-acetyl-5-thio-β-D-glucopyranosyl bromide (1) (Tetrahedron, vol. 49, p. 8977, 1993), 2-(4-ethylbenzyl)phenol (9), potassium carbonate and benzyl tri-n-butylammonium chloride were mixed in chloroform and heated at 60° C. However, it was completely impossible to obtain a glycosylation product. 2-(4-Ethylbenzyl)phenyl acetate was obtained as a by-product.

WORKUP

后处理

  1. customto obtain a glycosylation product