Toluene → 1,1-Dichloroethane

HRID 1297807Notes

Reaction equation

HRID 1297807 reaction equation
O1CCC[CH2:2]1.[O:6]1[CH2:11][CH2:10]OCC1.[C:12]1(C)[CH:17]=CC=[CH:14][CH:13]=1.[Cl:19][CH2:20][Cl:21]>CC(C)=O.CC(CC)=O.ClC1C=CC=CC=1>[Cl:19][CH:20]([Cl:21])[CH3:2].[C:11]1(=[O:6])[CH2:10][CH2:14][CH2:13][CH2:12][CH2:17]1

Participants

9

Reactant 4

HCID 1140TolueneHCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 312751,4-Dioxane

Product 2

HCID 63651,1-DichloroethaneHCID 7967Cyclohexanone

Reagents, catalysts & solvents 3

HCID 180AcetoneSolventHCID 6569Methyl Ethyl KetoneSolventHCID 7964ChlorobenzeneSolvent

Procedure

As a solvent used herein, tetrahydrofuran, dioxane, dioxoran, toluene, dichloromethane, monochlorobenzene, dichloroethane, cyclohexanone, ethyl methyl ketone, acetone can be provided. The solvents may be used singularly or in combination as a mixture.

Sources & evidence

ORD record
ord-a8eaa88b682849ac8c5dad4db382404a
Source dataset
uspto-grants-2007_07
Patent number
US07251437B2

Reaction notes

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