2,4,6-Tris((dimethylamino)methyl)phenol → Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

HRID 129901ノート

反応式

HRID 129901 の反応式
[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[OH:19])[CH3:3].[OH-].[Na+:21]>O>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[Na+:21]

参加物

4

反応物 2

HCID 70262,4,6-Tris((dimethylamino)methyl)phenolHCID 14798Sodium Hydroxide

生成物 1

HCID 23711567Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

53.1 g (0.2 mol) of 2,4,6-tris(dimethylaminomethyl)phenol and 100 ml of H2O are placed in a 500 ml round-bottomed flask having a magnetic stirrer and dropping funnel and, with stirring, 16.0 g (0.2 mol) of a 50% aqueous NaOH solution are added dropwise thereto. The clear, slightly yellow solution is concentrated by evaporation in a rotary evaporator at 70° C., and the residue is dried at 100° C./125 T (16.6×103Pa), yielding 55.1 g of sodium 2,4,6-tris(dimethylaminomethyl)phenolate in the form of a brownish solid of which the elemental analysis is as follows:

後処理

  1. concentrationThe clear, slightly yellow solution is concentrated by evaporation in a rotary evaporator at 70° C.
  2. customthe residue is dried at 100° C./125 T (16.6×103Pa)

出典と根拠

ORDレコード
ord-3c5191ce46fa44de922b527f60b69675
出典データセット
uspto-grants-1995_11
特許番号
US05470896

反応ノート

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