Lanthanum nitrate → Lanthanum tris(2,4,6-tris(dimethylaminomethyl)phenolate)

HRID 129903노트

반응식

HRID 129903 반응식
[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:3].[Na+].[N+]([O-])([O-])=O.[La+3:25].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O>C(O)CCC>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[La+3:25]

참가 물질

4

반응물 2

HCID 25122Lanthanum nitrateHCID 23711567Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

생성물 1

HCID 86749118Lanthanum tris(2,4,6-tris(dimethylaminomethyl)phenolate)

시약·촉매·용매 1

HCID 2631-Butanol용매

실험 절차

8.6 g (0.03 mol)of sodium 2,4,6-tris(dimethylaminomethyl)phenolate (preparation see Example 19) and 28 g of 1-butanol are placed in a 100 ml round-bottomed flask having a magnetic stirrer, and then 4.33 g (0.01 mol) of lanthanum nitrate are added. The solution is stirred for 45 minutes, and then the precipitated sodium nitrate is filtered off. A clear, dark-brown 25% accelerator solution of lanthanum tris(2,4,6-tris(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

후처리

  1. filtrationthe precipitated sodium nitrate is filtered off

출처 및 근거

ORD 기록
ord-b2c72d52ae8144f1941531a8c03448d5
출처 데이터셋
uspto-grants-1995_11
특허 번호
US05470896

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