HRID129903

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[La+3]

HCID25122

Lanthanum (III) nitrate

LaN3O9

结构：CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.[Na+]

HCID23711567

Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

C15H26N3NaO

PRODUCTS

生成物

结构：CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.[La+3]

HCID86749118

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID263

1-Butanol

C4H10O

PROCEDURE

实验过程

8.6 g (0.03 mol)of sodium 2,4,6-tris(dimethylaminomethyl)phenolate (preparation see Example 19) and 28 g of 1-butanol are placed in a 100 ml round-bottomed flask having a magnetic stirrer, and then 4.33 g (0.01 mol) of lanthanum nitrate are added. The solution is stirred for 45 minutes, and then the precipitated sodium nitrate is filtered off. A clear, dark-brown 25% accelerator solution of lanthanum tris(2,4,6-tris(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

WORKUP

后处理

filtrationthe precipitated sodium nitrate is filtered off

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b2c72d52ae8144f1941531a8c03448d5
来源数据集: uspto-grants-1995_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05470896
来源说明: uspto-grants-1995_11

反应 SMILES

[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:3].[Na+].[N+]([O-])([O-])=O.[La+3:25].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O>C(O)CCC>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[La+3:25]