Sodium → Calcium bis(2,4,6-tris-(dimethylaminomethyl)phenolate)

HRID 129905ノート

反応式

HRID 129905 の反応式
O.O.O.O.[N+]([O-])([O-])=O.[Ca+2:9].[N+]([O-])([O-])=O.[CH3:14][N:15]([CH2:17][C:18]1[CH:23]=[C:22]([CH2:24][N:25]([CH3:27])[CH3:26])[CH:21]=[C:20]([CH2:28][N:29]([CH3:31])[CH3:30])[C:19]=1[O-:32])[CH3:16].[K+].[Na]>C(O)CCC>[CH3:16][N:15]([CH2:17][C:18]1[CH:23]=[C:22]([CH2:24][N:25]([CH3:26])[CH3:27])[CH:21]=[C:20]([CH2:28][N:29]([CH3:31])[CH3:30])[C:19]=1[O-:32])[CH3:14].[CH3:16][N:15]([CH2:17][C:18]1[CH:23]=[C:22]([CH2:24][N:25]([CH3:26])[CH3:27])[CH:21]=[C:20]([CH2:28][N:29]([CH3:31])[CH3:30])[C:19]=1[O-:32])[CH3:14].[Ca+2:9]

参加物

5

反応物 3

HCID 5360545SodiumHCID 16211656Calcium nitrate tetrahydrateHCID 67845164Potassium (2,4,6-tris(dimethylaminomethyl)phenolate)

生成物 1

HCID 19370681Calcium bis(2,4,6-tris-(dimethylaminomethyl)phenolate)

試薬・触媒・溶媒 1

HCID 2631-Butanol溶媒

実験手順

In a 250 ml round-bottomed flask having a magnetic stirrer and reflux condenser, 12.3 g (0.052 mol) of calcium nitrate tetrahydrate are dissolved in 88.7 g of 1-butanol, and then 31.55 g (0.104 mol) of potassium (2,4,6-tris(dimethylaminomethyl)phenolate) (prepared in the same manner as the sodium salt according to Example 19) are added. The solution is stirred at reflux for 1 hour and then cooled. The precipitated potassium nitrate is filtered off. A clear, yellow 25% accelerator solution of calcium bis(2,4,6-tris-(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

後処理

  1. customIn a 250 ml round-bottomed flask having
  2. temperaturea magnetic stirrer and reflux condenser
  3. additionare added
  4. temperatureat reflux for 1 hour
  5. temperaturecooled
  6. filtrationThe precipitated potassium nitrate is filtered off

出典と根拠

ORDレコード
ord-6f6eb7321270447bb0f8041025465488
出典データセット
uspto-grants-1995_11
特許番号
US05470896

反応ノート

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