Lithium Hydroxide → Lithium 2,4,6-tris(dimethylaminomethyl)phenolate

反応式

[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[OH:19])[CH3:3].[OH-].[Li+:21]>>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[Li+:21]

参加物

反応物 2

HCID 3939Lithium Hydroxide

HCID 70262,4,6-Tris((dimethylamino)methyl)phenol

生成物 1

HCID 23711568Lithium 2,4,6-tris(dimethylaminomethyl)phenolate収率 100.1%

実験手順

Analogously to Example 19, starting from 53.1 g (0.2 mol) of 2,4,6-tris(dimethylaminomethyl)phenol and 9.2 g (0.2 mol) of lithium hydroxide there are obtained 54.3 g of lithium 2,4,6-tris(dimethylaminomethyl)phenolate in the form of an orange solid of which the elemental analysis is as follows:

出典と根拠

ORDレコード: ord-23f3457368d942959f585299ed7f612f
出典データセット: uspto-grants-1995_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05470896

反応ノート

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