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HRID133188

反应详情

EQUATION

反应方程式

HRID 133188 的结构方程式

REACTANTS

反应物

3
结构：CC(=O)O
HCID176

Acetic Acid

C2H4O2

结构：CC(=O)O[BH-](OC(C)=O)OC(C)=O.[Na+]
HCID5049666

Sodium triacetoxyborohydride

C6H10BNaO6

结构：Cc1ccc2[nH]c3c(cc(-c4cccc(C=O)c4)c(=O)n3C)c2c1
HCID86602343

未命名化合物

PRODUCTS

生成物

1
结构：Cc1ccc2[nH]c3c(cc(-c4cccc(CO)c4)c(=O)n3C)c2c1
HCID67387052

未命名化合物

收率 71%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

280 mg of the compound obtained in Stage A are placed in 10 ml of CH2Cl2 and the minimum amount of AcOH to dissolve the compound, 375 mg of NaBH(OAc)3 are added and then the mixture is left stirring at AT for 18 hours. The reaction medium is evaporated and the residue is taken up in AcOEt and then filtration is carried out to produce 200 mg of the expected compound.

WORKUP

后处理

  1. additionare added
  2. waitthe mixture is left
  3. customThe reaction medium is evaporated
  4. filtrationfiltration