HRID133634

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID784

Hydrogen peroxide

H2O2

HCID7366

tert-Butylbenzene

C10H14

结构：CC1(C)CC(OC(=O)CCCCC(=O)OC2CC(C)(C)N(O)C(C)(C)C2)CC(C)(C)N1O

HCID57039687

未命名化合物

PRODUCTS

生成物

结构：CC(C)(CON1C(C)(C)CC(OC(=O)CCCCC(=O)OC2CC(C)(C)N(OCC(C)(C)c3ccccc3)C(C)(C)C2)CC1(C)C)c1ccccc1

HCID50943318

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

The title compound is prepared from the reaction of bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) adipate, aqueous hydrogen peroxide, ferric chloride hexahydrate; acetonitrile, and tert-butylbenzene following a procedure similar to that of Example 6.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-64b61b75dc6a411aa60355191c3a0acd
来源数据集: uspto-grants-2008_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07390904B2
来源说明: uspto-grants-2008_06

反应 SMILES

[C:1]([O:21][CH:22]1[CH2:27][C:26]([CH3:29])([CH3:28])[N:25]([OH:30])[C:24]([CH3:32])([CH3:31])[CH2:23]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[N:12]([OH:17])[C:11]([CH3:19])([CH3:18])[CH2:10]1)=[O:7].OO.[C:35]([C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)([CH3:38])([CH3:37])[CH3:36]>C(#N)C>[C:1]([O:21][CH:22]1[CH2:23][C:24]([CH3:32])([CH3:31])[N:25]([O:30][CH2:36][C:35]([CH3:38])([C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)[CH3:37])[C:26]([CH3:29])([CH3:28])[CH2:27]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[N:12]([O:17][CH2:36][C:35]([CH3:38])([C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)[CH3:37])[C:11]([CH3:19])([CH3:18])[CH2:10]1)=[O:7]