HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methacryloyl chloride → N-[3-(Hydroxymethyl)-4-nitrophenyl]-2-methylprop-2-enamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methacryloyl chloride | HCID 13528 | — |
| Reactant | (5-Amino-2-nitrophenyl)methanol | HCID 13238551 | — |
| Product | N-[3-(Hydroxymethyl)-4-nitrophenyl]-2-methylprop-2-enamide | HCID 67527004 | — |
Reaction Steps
N-(3-Hydroxymethyl-4-nitrophenyl)-2-methylacrylamide was prepared as described in Example 1a starting from (5-Amino-2-nitrophenyl)methanol and methacryloyl chloride. 1H NMR (400 MHz, DMSO-d6): 1.97 (3H, s), 4.85 (2H, d, J=5.2 Hz), 5.56 (1H, t, J=5.2 Hz), 5.61 (1H, s), 5.90 (1H, s), 7.93 (1H, dd, J=9.0 Hz, J=2.1 Hz), 8.11 (1H, d, J=9.0 Hz), 8.20 (1H, d, J=2.1 Hz), 10.32 (1H, s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07390923B2 |
| Source dataset | uspto-grants-2008_06 |
| ORD ID | ord-8fbfa66a81f142b6bd437f6f3357c304 |
| Source note | uspto-grants-2008_06 |