Toluene → Methyl 2-[6-[[3-[4-(1,1-dioxothian-4-yl)oxy-2,6-dimethylphenyl]phenyl]methoxy]-2,3-dihydro-1-benzofuran-3-yl]acetate

HRID 134232Notes

Reaction equation

HRID 134232 reaction equation
[CH2:41]([P:42]([CH2:43][CH2:44][CH2:45][CH3:46])[CH2:47][CH2:48][CH2:49][CH3:50])[CH2:51][CH2:52][CH3:53].[CH3:72][c:73]1[cH:74][cH:75][cH:76][cH:77][cH:78]1.[CH3:79][CH2:80][CH2:81][CH2:82][CH2:83][CH3:84].[N:54]([C:55]([N:56]1[CH2:57][CH2:58][CH2:59][CH2:60][CH2:61]1)=[O:62])=[N:63][C:64]([N:65]1[CH2:66][CH2:67][CH2:68][CH2:69][CH2:70]1)=[O:71].[O:16]=[S:17]1(=[O:40])[CH2:18][CH2:19][CH:20]([O:23][c:24]2[cH:25][c:26]([CH3:39])[c:27](-[c:31]3[cH:32][c:33]([CH2:37][OH:38])[cH:34][cH:35][cH:36]3)[c:28]([CH3:30])[cH:29]2)[CH2:21][CH2:22]1.[OH:1][c:2]1[cH:3][c:4]2[c:5]([cH:14][cH:15]1)[CH:6]([CH2:9][C:10](=[O:11])[O:12][CH3:13])[CH2:7][O:8]2>>[O:1]([c:2]1[cH:3][c:4]2[c:5]([cH:14][cH:15]1)[CH:6]([CH2:9][C:10](=[O:11])[O:12][CH3:13])[CH2:7][O:8]2)[CH2:37][c:33]1[cH:32][c:31](-[c:27]2[c:26]([CH3:39])[cH:25][c:24]([O:23][CH:20]3[CH2:19][CH2:18][S:17](=[O:16])(=[O:40])[CH2:22][CH2:21]3)[cH:29][c:28]2[CH3:30])[cH:36][cH:35][cH:34]1

Participants

7

Reactant 6

HCID 1140TolueneHCID 8058HexaneHCID 13831TributylphosphineHCID 730421,1'-(Azodicarbonyl)dipiperidineHCID 57345855Methyl 2-(6-hydroxy-2,3-dihydrobenzofuran-3-yl)acetateHCID 59342608{4'-[(1,1-dioxidotetrahydro-2H-thiopyran-4-yl)oxy]-2',6'-dimethylbiphenyl-3-yl}methanol

Product 1

HCID 72259619Methyl 2-[6-[[3-[4-(1,1-dioxothian-4-yl)oxy-2,6-dimethylphenyl]phenyl]methoxy]-2,3-dihydro-1-benzofuran-3-yl]acetate

Sources & evidence

ORD record
ord-a51407325369418794fdc0628e92436e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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