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HRID1350292

反应详情

EQUATION

反应方程式

HRID 1350292 的结构方程式

REACTANTS

反应物

2
结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：CCOC(=O)C(=CC1CCOCC1)c1ccc(SC2CC2)cc1
HCID67484543

Ethyl 4-(cyclopropylthio)-α-[(tetrahydro-2H-pyran-4-yl)methylene]benzeneacetate

C19H24O3S

PRODUCTS

生成物

1
结构：CCOC(=O)C(=CC1CCOCC1)c1ccc(S(=O)C2CC2)cc1
HCID68625275

未命名化合物

PROCEDURE

实验过程

Partial oxidation of ethyl 2-(4-cyclopropylsulfanylphenyl)-3-(tetrahydropyran-4-yl)acrylate (see Preparation 22, 3.14 g, 9.44 mmol) with mCPBA, employing the protocol described above in Preparation 18, furnished ethyl 2-(4-cyclopropanesulfinylphenyl)-3-(tetrahydropyran-4-yl)acrylate: m/z (ES+)=349.2 [M+H]+. Sanctification of this ester (1.15 g, 3.3 mmol), using the procedure described in Preparation 25, afforded the title compound: m/z (ES+)=641.4 [2M+H]+.

WORKUP

后处理

  1. customdescribed above in Preparation 18