Acetonitrile → HCID 21889441, compound

HRID 1352180Notes

Reaction equation

HRID 1352180 reaction equation
[CH:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[C:8]([CH:13]([CH3:15])[CH3:14])[CH:7]=[C:6]([CH:16]([CH3:18])[CH3:17])[C:5]=1[S:19]([OH:22])(=[O:21])=[O:20])([CH3:3])[CH3:2].C(#N)C.[Ag:26]=O>CC(C)=O>[CH:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[C:8]([CH:13]([CH3:14])[CH3:15])[CH:7]=[C:6]([CH:16]([CH3:18])[CH3:17])[C:5]=1[S:19]([O-:22])(=[O:21])=[O:20])([CH3:2])[CH3:3].[Ag+:26]

Participants

5

Reactant 3

HCID 6342AcetonitrileHCID 92152Silver(II) oxideHCID 218894203-Nitro-2,4,6-tri(propan-2-yl)benzene-1-sulfonic acid

Product 1

HCID 21889441HCID 21889441, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Into a flask were charged 20 parts of 2,4,6-triisopropyl-3-nitrobenzenesulfonic acid, 80 parts of acetonitrile and 40 parts of acetone, and the mixture was stirred at room temperature for 16 hours. To this was added 7.46 parts of silver oxide, and the mixture was stirred at room temperature for 16 hours, and then filtered and concentrated to obtain 23.68 parts of silver 2,4,6-triisopropyl-3-nitrobenzenesulfonate.

Workup

  1. stirringthe mixture was stirred at room temperature for 16 hours
  2. filtrationfiltered
  3. concentrationconcentrated

Sources & evidence

ORD record
ord-69941d1e013c4be3a0ce3a0526dd9244
Source dataset
uspto-grants-2007_05
Patent number
US07220532B2

Reaction notes

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